基盤研究A(2007-2010年度、代表:伊原博隆)に関連した研究成果一覧


学術論文
  1. Novel Approach for the Separation of Shape-Constrained Isomers with Alternating Copolymer-Grafted Silica in Reversed-Phase Liquid Chromatography.
    Analytical Chemistry, Vol.82, pp.3320-3328, 2010
    A. K. Mallik, T. Sawada, M. Takafuji, H. Ihara

  2. New strategy for drastic enhancement of selectivity via chemical modification of counter anions in ionic liquid polymer phase.
    Chemical Communications, Vol.46, pp.8740-8742, 2010.
    H. Qiu, M. Takafuji, T. Sawada, X. Liu, S. Jiang, H. Ihara

  3. Preparation of high selective HPLC packing materials based on alternating copolymer-grafted silica.
    Journal of Separation Science, Vol.33, pp.2977-2989, 2010.
    A. K. Mallik, M. Takafuji, H. Ihara

  4. Investigation of π-π and ion-dipole interactions on 1-allyl-3-butylimidazolium ionic liquid-modified silica stationary phase in reversed-phase liquid chromatography.
    Journal of Chromatography A, Vol.1217, pp.5190-5196, 2010.
    H. Qiu, X. Liu, S. Jiang, M. Takafuji, H. Ihara

  5. Synthesis and characterization of poly(ionic liquid)-grafted silica hybrid materials through surface-radical chain-transfer polymerization and aqueous anion-exchange.
    Materials Letters, Vol.64, pp.1653-1655, 2010.
    H. Qiu, T. Sawada, S. Jiang, H. Ihara

  6. Complete chromatographic separation of steroids including 17α- and 17β-estradioles using carbazole-based polymeric organic phase in both revered and normal phase HPLC.
    Analytical and Bioanalytical Chemistry, Vol.397, pp.623-629, 2010.
    A. K. Mallik, K. Shingo, U. G. Gautam, T. Sawada, M. Takafuji, H. Ihara

  7. Chromatographic analysis of polycyclic aromatic hydrocarbons by p-electron-containing polymeric organic phase-grafted on silica.
    Polycyclic Aromatic Hydrocarbons: Pollution, Health, Effects and Chemistry, Nova Publishers, Edited by Pierre A. Haines and Milton D. Hendrickson, Chapter 11, pp.265-294, 2011.
    M. M. Rahman, A. Rana, U. G. Gautam, M. Takafuji, H. Ihara



  8. A facile preparation method for self-assembled monolayers with silica particles on polystyrene-based microspheres.
    Materials Chemistry and Physics, Vol.114, pp.1-5, 2009.
    H. Ihara, S. Kubota, A. Uchimura, Y. Sakai, T. Wakiya, M. M. Rahman, S. Nagaoka, M. Takafuji

  9. Thermodynamic investigations on shape selective separation behaviors of poly(4-vinylpyridine)-grafted silica for PAHs in both normal-phase and reversed-phase high-performance liquid chromatography.
    Journal of Chromatography A, Vol.1216, pp.3571-3577, 2009.
    Usha Ghimire Gautam, Mani Prasad Gautam, Tsuyoshi Sawada, Makoto Takafuji, Hirotaka Ihara

  10. Evaluation of selectivity for l-glutamide-derived highly ordered assemblies in reversed-phase high-performance liquid Chromatography.
    Talanta, Vol.77, p.1228-1237, 2009.
    M. Mizanur Rahman, M. Takafuji, H. Ihara

  11. Tuning of the molecular packing structure of comb-shaped polymer-grafted silica by using surface-initiated ATRP to enhance the molecular-shape selectivity towards polycyclic aromatic hydrocarbons.
    European Polymer Journal, Vol.45, pp. 1811-1819, 2009.
    Abul K. Mallik, M. Takafuji, H. Ihara

  12. Controllable shape-selectivity based on highly-ordered carbonyl and methyl groups in simple -structural polypeptide on silica.
    Journal of Chromatography A, Vol.1216, pp.6170-6176, 2009.
    A. Shundo, A. K. Mallik, T. Sakurai, M. Takafuji, S. Nagaoka, H. Ihara

  13. Poly(2-N-carbazolylethyl acrylate)-modified silica as a new polymeric stationary phase for reversed-phase high-performance liquid chromatography.
    Journal of Chromatography A, Vol.1216, pp.7422-7426, 2009.
    U. G. Gautam, T. Sawada, M. P. Gautam, M. Takafuji, H. Ihara

  14. Molecular-shape selectivity tuned by donor-acceptor type copolymers as organic phase in reversed-phase high-performance liquid chromatography.
    Journal of Chromatography A, Vol.1216, pp.7433-7439, 2009.
    Abul K. Mallik, M. Takafuji, H. Ihara

  15. Effect of the direction of ester linkage on molecular shape selectivity through multiple carbonyl pi-interaction with octadecyl chain branched polymers as organic phases in reversed-phase high-performance liquid chromatography.
    Journal of Chromatography A, 1216, pp.7440-7445, 2009.
    A. Rana, M. Takafuji, H. Ihara

  16. Self-assembled organic phase for RP/HPLC
    Encyclopedia of Chromatography, 3rd Edition, CRC Press, Edited by Jack Cazes, pp.2149-2156, 2009.
    Abul K. Mallik, M. M. Rahman, M. Takafuji, H. Ihara, S. Nagaoka


  17. Synthesis, Self-Assembling Properties and Atom Transfer Radical Polymerization of Alkylated L-Phenylalanine-Derived Monomeric Organogel from Silica: A New Approach to Prepare Packing Materials for High Performance Liquid Chromatography.
    Chemistry - A European Journal, Vol.14, pp.1312-1321, 2008.
    M. M. Rahman, M. Czaun, M. Takafuji, H. Ihara

  18. Facile synthesis of high-density poly(octadecylacrylate) grafted silica for RP-HPLC by surface initiated atom transfer radical polymerization.
    Journal of Chromatography A, Vol 1187, pp 119-127, 2008.
    Abul K. Mallik, M. M. Rahman, M. Czaun, M. Takafuji, H. Ihara

  19. High Retentivity and selectivity for polycyclic aromatic hydrocarbons with poly(4-vinylpyridine)-grafted silica in normal-phase high performance liquid chromatography.
    Journal of Chromatography A, Vol.1189, pp.77-82, 2008.
    Usha Ghimire Gautam, Atsuomi Shundo, Mani Prasad Gautam, Makoto Takafuji, Hirotaka Ihara.

  20. Enhancement of retentivity and selectivity for PAHs in NP-HPLC by high dense immobilization of poly(4-vinylpyridine) as an organic phase on silica
    Analytical Sciences, Vol.24, pp.615-621, 2008.
    Usha Ghimire Gautam, Mani Prasad Gautam, Tsuyoshi Sawada, Makoto Takafuji, Hirotaka Ihara.

  21. Surface-initiated living radical polymerization of self-assembling L-phenylalanine derived monomer from silica for RP-HPLC application.
    Journal of Polymer Science Part A: Polymer Chemistry (Rapid Communications), Vol.46, pp.6664-6671, 2008
    M. Czaun, M. Mizanur Rahman, M. Takafuji, H. Ihara.

  22. Preparation, Telomerization, immobilization and application of N-alkyl L-phenylalanine-derived polymerizable organogelator for reversed-phase high-performance liquid chromatography.
    Journal of Chromatography A, Vol.1203, p.59-66, 2008.
    M. Mizanur Rahman, M. Takafuji, H. Ihara.

  23. Synthesis and evaluation of molecular recognizability by RP-HPLC for N-alkyl-beta-alanine-L-phenylalanine-derived organic phase with self-Assembling ability.
    Analytical and Bioanalytical Chemistry, Vol.392, pp.1197-1208, 2008.
    M. Mizanur Rahman, M. Takafuji, H. Ihara.


  24. Selectivity Enhancement for trans-2-(2,3-Anthracenedicarboximido)cyclohexane-derived Diastereomers in HPLC by Using Ordered Organic Stationary Phase.
    Analytical Sciences, Vol.23, pp. 311-315, 2007.
    A. Shundo, M. Fukui, M. Takafuji, K. Akasaka, H. Orui, D. Berek, H. Ihara.

  25. A New Route for Preparation of High-density Organic Phase to High Selective HPLC by Atom Transfer Radical Polymerization of Octadecyl Acrylate on Silica.
    Chemistry Letters, Vol.36, pp.1460-1461, 2007.
    Abul K. Mallik, M. M. Rahman, M. Czaun, M. Takafuji, H. Ihara

学会発表

  1. Molecular-shape selective HPLC through copolymer-based organic phase with controlled polymer main chain.
    ACS Spring 2010 National Meeting & Exposition, San Francisco, 2010.3
    Abul K. Mallik, Tsuyoshi Sawada, Makoto Takafuji, Hirotaka Ihara

  2. Preparation of a core-shell hybrid with a silica particle monolayer shell by self-assembling copolymerization using polymerizable emulsifier.
    11th Pacific Polymer Conference, Cairns, Australia, 2009. 12
    A. Uchimura, S. Kubota, T. Wakiya, S. Nagaoka, M. Takafuji, H. Ihara

  3. Developmet of New Polymer-Grafted Adsorbents for High-Selective Liquid Chromatography [oral]
    ICAST 2009, Seoul, Korea, 2009.12
    Abul K. Mallik, Makoto Takafuji, Hirotaka Ihara

  4. Evaluation of carbazole-based HPLC stationary phase through separation of steroids [poster]
    ICAST 2009, Seoul, Korea, 2009.12
    Kaori Shingo, Abul K. Mallik, Usha Ghimire Gautam, Tsuyoshi Sawada, Makoto Takafuji, Hirotaka Ihara

  5. 弱い相互作用の効率的な活用による分子形状識別の実現
    特別講演会, 京都大学, 2009. 12
    伊原 博隆

  6. Control of Surface Roughness of Core-Shell Particles with a Nano-sized Silica Particles Monolayer. [poster, Outstanding Poster Award]
    2009 Pusan-Kyeongnam/Kyushu-Seibu Joint Symposium on High Polymers (14th) and Fibers (12th), The Inamori Auditorium, Kagoshima University, 2009.10
    Atsumi Uchimura, Sachiyo Kubota, Takeshi Wakiya, Shoji Nagaoka, Makoto Takafuji, Hirotaka Ihara

  7. Preparation of Core/Shell Particles by Self Assembling of Silica Particles at O/W Interface [oral]
    高分子討論会, 熊本大学, 2009.9
    Atsumi UCHIMURA, Sachiyo KUBOTA, Takeshi WAKIYA, Shoji NAGAOKA, Makoto TAKAFUJI, and Hirotaka IHARA

  8. A Facile Preparation Method for Core-Shell Particles with Controlled Roughness on the Shell by Self-Assembling Suspension Copolymerizatio [poster]
    高分子討論会, 熊本大学, 2009.9
    Sachiyo KUBOTA, Atsumi UCHIMURA, Takeshi WAKIYA, Makoto TAKAFUJI, and Hirotaka IHARA

  9. Effect of High Density Poly (Vinyl octadecanoate) Grafted Silica Stationary Phase on Physiochemical Properties and Shape Selectivity Enhancement of PAHs in RP-HPLC [poster]
    高分子討論会, 熊本大学, 2009.9
    Ashequl Alam RANA, Makoto TAKAKAFUJI, and Hirotaka IHARA

  10. Alternating Copolymerization on Silica and its Application for the Unique Separation of Shape-Constrained Isomers [poster]
    高分子討論会, 熊本大学, 2009.9
    Abul K. MALLIK, Makoto TAKAFUJI, Tsuyoshi SAWADA, and Hirotaka IHARA

  11. Facile Preparation Method for Core-Shell Microspheres with Controlled Surface Roughness [oral]
    IUPAC 45th General Assembly & IUPAC 42nd Congress, Glasgow, UK, 2009.8
    H. Ihara, S. Kubota, A. Kubota, T. Wakiya, T. Sawada, M. Takafuji

  12. Unusual separation of carotene and tocopherol isomers using alternating copolymer-grafted silica stationary phase in HPLC [poster]
    IUPAC 45th General Assembly & IUPAC 42nd Congress, Glasgow, UK, 2009.8
    A. K. Mallik, M. Takafuji, H. Ihara

  13. Synthesis of Alternating Copolymer-Grafted Silica: A New Approach for High Selective HPLC [poster]
    34th International Symposium on High-Peformance Liquid Phase Separations and Related Techniques, Dresden, Germany, 2009.6
    H. Ihara, A. K. Mallik, M. Takafuji

  14. Carbazole-based Polymeric Organic Phase on Silica for Molecular Shape-selective High-performance Liquid Chromatography [poster]
    34th International Symposium on High-Peformance Liquid Phase Separations and Related Techniques, Dresden, Germany, 2009.6
    U. Ghimire, A. K. Mallik, T. Sawada, M. Takafuji, H. Ihara


  15. Synthesis of Poly(4-vinylpyridine-co-methyl acrylate)-Grafted Silica Stationary Phase as Polymeric Organic Phase for Selectivity Tuning towards PAHs in Reversed-Phase High Performance Liquid Chromatography.
    HPLC 2008 Kyoto, Kyoto, 2008.12
    Abul K. Mallik, Makoto Takafuji, Hirotaka Ihara

  16. Effect of direction of ester linkage on molecular shape selectivity through multiple carbonyl π-interaction with octadecyl chain-branched polymers as organic phases in RP-HPLC.
    HPLC 2008 Kyoto, Kyoto, 2008.12
    Ashequl A.Rana, Makoto Takafuji, Hirotaka Ihara

  17. Poly(N-vinylcarbazole)-grafted Silica and Poly(2-N-carbazolylethyl acrylate)-grafted Silica as New Polymeric Adsorbents for both Normal-phase and Reversed-phase High-performance Liquid Chromatography
    HPLC 2008 Kyoto, Kyoto, 2008.12
    Usha Ghimire Gautam, Mani P. Gautam, Makoto Takafuji, Hirotaka Ihara

  18. Facile Preparation of Organic-Inorganic Core-Shell Composites with Monodispersed Silica Particles-Monolayer on Polystyrene-Based Microspheres
    30th Australasian Polymer Symposium (30APS), Melbourne, Australia, 2008.12
    S. Kubota, A. Uchimura, T. Wakiya, M. Takafuji, S. Nagaoka, H. Ihara

  19. シリカ粒子モノレーヤーをシェルにもつポリマー微粒子の簡便な作製法
    第57回高分子討論会,大阪府立大学, 2008.9
    内村淳美,久保田幸代,高藤誠,伊原博隆

  20. Poly(4-vinylpyridine)-grafted silica as a versatile packing material for both normal-phase and reversed-phase HPLC
    236th ACS National Meeting, Philadelphia, USA, 2008.8
    Usha Ghimire Gautam, Mani Prasad Gautam, T. Sawada, M. Takafuji, H. Ihara

  21. Poly(2-N-carbazolylethyl acrylate)-modified silica as a new polymeric stationary phase for RP-HPLC: Enhanced retentivity and selectivity due to pi-pi interaction
    236th ACS National Meeting, Philadelphia, USA, 2008.8
    Usha Ghimire Gautam, Mani Prasad Gautam, M. Takafuji, H. Ihara

  22. シリカ微粒子モノレイヤーをシェルとするコア−シェル粒子の簡便な作製法
    第45回化学関連支部合同九州大会,北九州国際会議場, 2008.7
    久保田 幸代,内村 淳美,堺 勇樹,脇屋 武司,高藤 誠,伊原 博隆

  23. Selectivity Enhancement in RP-HPLC by Tuning the Molecular Packing Structure of Polymeric Organic Phase on Silica
    91st Canadian Chemistry Conference and Exhibition (CSC 2008), Edmonton, Canada, 2008.5
    A. K. Mallik, M. M. Rahman, M. Czaun, M. Takafuji, H. Ihara

  24. Remarkable Increase of Selectivity for PAHs with Slight Change of Orientation of poly(4-vinylpyridine) as an Organic Phase in HPLC.
    32nd International Symposium on High Performance Liquid Phase Separations and Related Techniques, Baltimore, USA, 2008.5
    Usha Ghimire Gautam, Makoto Takafuji, Hirotaka Ihara

  25. Inorganic-organic Hybrid Materials for Chromatographic Separation Prepared by Grafting of N-Alkyl L-Phenylalanine-derived Polymerizable Organogelator on to Silica.
    32nd International Symposium on High Performance Liquid Phase Separations and Related Techniques, Baltimore, USA, 2008.5
    Mohammed Mizanur Rahman, Abul K. Mallik, Miklos Czaun, Makoto Takafuji, Hirotaka Ihara


  26. Surface-Initiated Living Radical Polymerization of Self-Assembling L-Phenylalanine Derived Monomer from Silica: A Facile Technique for the Preparation of High-Density Chromatographic Support for RP-HPLC Application
    Singapore International Chemistry Conference (SICC-5), Singapore, 2007.12
    M. Mizanur Rahman, Miklos Czaun, Abul K. Mallik, Makoto Takafuji, Hirotaka Ihara

  27. Enhanced Molecular Shape Selectivity by Surface-Initiated Atom Transfer Radically Polymerized Octadecyl Acrylate from Silica
    Singapore International Chemistry Conference (SICC-5), Singapore, 2007.12
    M. Mizanur Rahman, Miklos Czaun, Abul K. Mallik, Makoto Takafuji, Hirotaka Ihara

  28. Synthesis and surface-initiated polymerization of N-octadecyl-L-Phenylalanine-derived monomer from silica to prepare high density stationary phase for HPLC.
    10th Pacific Polymer Conference (PPC 10), Kobe (Japan), 2007.12
    M. Czaun, M. M. Rahman, M. Takafuji, H. Ihara

  29. 有機分子ゲルとシリカゲルの複合
    第4回相模触媒セミナー, 相模中央化学研究所, 2007.11
    伊原博隆

  30. Influence of Immobilization Routes on the Selectivity Enhancement for Polycyclic Aromatic Hydrocarbons with Poly(4-vinylpyridine)-modified Slica in High Performance Liquid Chromatography
    4nd International Forum "New Waves in Supramolecular Chemistry and Superstructured Materials" (IFSC2007 Fall), Kumamoto, Japan, 2007.9
    G. Usha, M. Takafuji, H. Ihara

  31. Glutamide-Derived Self Assembled Lipid as Novel HPLC Packing Materials: Enhanced Selectivity for Aromatic Hydrocarbons
    12th IUPAC International Symposium on MacroMolecular Complexes(MMC-12),Fukuoka, Japan, 2007.
    M. Mizanur Rahman, M. Takafuji and H. Ihara

  32. Preparation of High-Density Chromatographic Organic Phase by Surface Initiated Atom Transfer Radical Polymerization for RP-HPLC
    12th IUPAC International Symposium on MacroMolecular Complexes(MMC-12),Fukuoka, Japan, 2007.
    M. Mizanur Rahman, Abul K. Mallik, M. Czaun, M. Takafuji and H. Ihara

  33. Enhanced molecular-shape selectivity with highly-ordered structures of poly(octadecyl acrylate) on porous silica gels
    13th International Symposium on Separation Sciences, Strbske Pleso, Slovak, 2007.6
    M. Takafuji, A. Shundo, R. Nakashima, H. Ihara

  34. High-Selective Reversed-Phase Liquid Chromatography by pi-Electron-Containing Polymer-Grafted Silica
    13th International Symposium on Separation Sciences, Strbske Pleso, Slovak, 2007.6
    A. Shundo, M. Takafuji, S. Nagaoka, H. Ihara

  35. Glutamide Based Noncrystalline Lipid Grafted Silica for RP-HPLC International symposium, Advances in Chromatography and Electrophoresis 2007 & Chiranal 2007, Olomouc, Czech Republic
    M. Takafuji, M. M. Rahman, A. Shundo, H. Ihara

  36. Chiral Discrimination by Using b-Structural Poly(L-Alanine) as Organic Stationary Phase in RP-HPLC
    International symposium, Advances in Chromatography and Electrophoresis 2007 & Chiranal 2007, Olomouc, Czech Republic
    A. Shundo, M. Takafuji, S. Nagaoka, H. Ihara

  37. High-Selective Normal-Phase Liquid Chromatography for Polycyclic Aromatic Hydrocarbons by b-Structural Poly(L-Alanine)-Grafted Silica
    31th International Symposium & Exhibit on High Performance Liquid Phase Separations & Related Techniques (HPLC-2007), Ghent, Belgium, 2007.6
    A. Shundo, T. Sakurai, M. Takafuji, H. Ihara.

  38. Glutamide Derivatives as Novel Molecular Recognitive Packing Materials for RP-HPLC
    31th International Symposium & Exhibit on High Performance Liquid Phase Separations & Related Techniques (HPLC-2007), Ghent, Belgium, 2007.6
    M. M. Rahman, M. Takafuji, H. Ihara.

  39. Versatility of Poly(4-vinylpyridine) as a Polymeric Liquid Stationary Phase in Normal Phase High Performance Liquid Chromatography
    31th International Symposium & Exhibit on High Performance Liquid Phase Separations & Related Techniques (HPLC-2007), Ghent, Belgium, 2007.6
    U. Ghimire, M. P. Gautam, A. Shundo, M. Takafuji, H. Ihara.

  40. Poly(4-vinylpyridine) as an organic stationary phase for separation of polycyclic aromatic hydrocarbons.
    International Conference on Emerging Issues on Research and Development, Kathmandu, Nepal, 2007.4
    Usha Ghimire Gautam, Mani Prasad Gautam, Atsuomi Shundo, Makoto Takafuji, Hirotaka Ihara